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Glutathione, Oxidative Stress and Mitochondrial Function in COVID-19

Early Phase 1
Terminated
Conditions
Covid19
Interventions
Dietary Supplement: Alanine
Dietary Supplement: Glycine
Dietary Supplement: N-acetylcysteine
Registration Number
NCT04703036
Lead Sponsor
Baylor College of Medicine
Brief Summary

COVID-19 is associated with increased mortality, and has been linked to a 'cytokine inflammatory storm'. Populations at higher risk of COVID complications and mortality include the elderly, diabetic patients and immunocompromised patients (such as HIV), and the investigators have studied these 3 populations over the past 20 years and have found that they all have deficiency of the endogenous antioxidant protein glutathione (GSH), elevated oxidative stress, inflammation, impaired mitochondrial function, immune dysfunction, and endothelial dysfunction.

It is known and established that GSH adequacy is necessary for neutralizing harmful oxidative stress, and that elevated oxidative stress appears to promote mitochondrial dysfunction. The combination of oxidative stress and mitochondrial dysfunction have also been linked to inflammation, immune dysfunction, and endothelial dysfunction. In prior studies in aging, the investigators have also identified that supplementing glutathione precursor amino-acids glycine and cysteine (provided as N-acetylcysteine) improves GSH deficiency and mitochondrial function, and lowers oxidative stress, inflammation, and endothelial dysfunction. The investigators have coined the term GlyNAC to refer to the combination of glycine and N-acetylcysteine.

This study will evaluate the prevalence and extent of these defects in patients with COVID-19 admitted to the hospital, and the response to supplementing GlyNAC or placebo for 2-weeks. Because patients with COVID-19 are also being reported to have fatigue and cognitive impairment, the investigators will also measure fatigue and cognition at admission, 1-week and 2-weeks after beginning supplementation. The supplementation is stopped after completing 2-weeks, and these outcomes will be measured again after 4-weeks and 8-weeks after stopping supplementation.

Detailed Description

This study will investigate associated defects in the following two populations of patients with COVID-19:

Hospitalized patients admitted for COVID-19 will sign an informed consent form, and be randomized to receive either active (Glycine plus N-acetylcysteine) or a placebo (alanine) supplementation for 2-weeks. On day-0, the participants will have a single blood draw to measure measure oxidative stress, Glutathione levels, inflammatory cytokines, endothelial dysfunction, mitochondrial dysfunction, immune dysfunction, and complete questionnaires to assess fatigue, activity and cognition. Additional clinical and lab information will be obtained from the hospital electronic medical records. These measurements will be repeated 1-week and 2-weeks after starting supplementation, and at 4-weeks and 8-weeks after stopping supplementation.

Recruitment & Eligibility

Status
TERMINATED
Sex
All
Target Recruitment
4
Inclusion Criteria
  • Age 55-85y;
  • Diagnosis of COVID-19;
  • Hospitalized patients.
Exclusion Criteria
  • Active heart disease or active cancer at time of recruitment;
  • Patients in Intensive Care Unit at the time of recruitment;
  • Patents with alanine transaminase and aspartate transaminase greater than 5 times the upper limit of normal at any time;
  • Patients requiring >4L per minute of oxygen support at the time of recruitment.

Study & Design

Study Type
INTERVENTIONAL
Study Design
PARALLEL
Arm && Interventions
GroupInterventionDescription
Placebo armAlanineThe placebo arm is alanine
Active armGlycineThe active supplements are glycine and N-acetylcysteine
Active armN-acetylcysteineThe active supplements are glycine and N-acetylcysteine
Primary Outcome Measures
NameTimeMethod
Change in Glutathione concentrationsDay 0, 3-days, 1-week, 2-weeks, 6-weeks, 10-weeks

Glutathione levels will be measured in red-blood cells

Change in Ordinal scaleDay 0, 1-week, 2-weeks

This is a scale developed by the World-Health Organization for COVID trials. The clinical condition of each participant will be determined using this scale at 3 time points - Day 0, after 1-week and after-2weeks of supplementation

Change in Interleukein 6 concentrationsDay 0, 3-days, 1-week, 2-weeks, 6-weeks, 10-weeks

Plasma IL-6 concentrations

Secondary Outcome Measures
NameTimeMethod
Change in marker of damage due to oxidative stressDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Plasma concentrations of F2-isoprostanes

Change in inflammatory cytokinesDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Plasma concentrations of TNFa, hsCRP, IL-10, PAI-1, D-dimer

Change in circulating marker of memoryDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Plasma BDNF concentrations

Change in oxidative stressDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Plasma concentrations of TBARS

Change in functionDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Measured using the Katz-activities of daily living

Change in mitochondrial energeticsDay 0 1-week, 2-weeks, 6-weeks, 10-weeks

Energetics measured by high-resolution respirometry in peripheral blood monocytes

Change in cognitionDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Measured using Montreal cognitive assessment which ranges from 0-30

Change in fatigueDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

Measured using the Facit-F fatigue scale

Change in immune functionDay 0, 1-week, 2-weeks, 6-weeks, 10-weeks

The trial will evaluate if COVID-related disease severity is associated with NK cell deficiency and antigen presenting cell production of IL-6 and TNF.

Trial Locations

Locations (1)

Baylor College of Medicine

🇺🇸

Houston, Texas, United States

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