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Phase I Study of PH100 (Ecklonia Cava Phlorotannins)

Phase 1
Completed
Conditions
Safety Issues
Interventions
Drug: Placebo
Drug: PH100 100mg
Drug: PH100 200mg
Drug: PH100 400mg
Drug: PH100 800mg
Drug: PH100 1200mg
Drug: PH100 1600mg
Registration Number
NCT04335045
Lead Sponsor
Phloronol Inc.
Brief Summary

The purpose of this study was to determine the safety and tolerability of PH100, a purified phlorotannins from a brown alga Ecklonia cava and the pharmacokinetics of its major compounds 8,8'-bieckol, dieckol, and phlorofucofuroeckol A (PFF-A), after single, ascending, oral doses of PH100 Capsules (over-encapsulated tablets) in healthy adult volunteers.

Detailed Description

This was a single-center, randomized, double-blind, placebo-controlled, single ascending dose study in healthy volunteers in which subjects received either placebo or a 100 mg, 200 mg, 400 mg, 800 mg, 1200 mg, or 1600 mg dose of PH100 capsules (over-encapsulated tablets containing purified Ecklonia cava phlorotannins as an active ingredient) in escalating dose groups (six cohorts). A total of 48 subjects were enrolled. Each cohort comprised eight subjects. Within each cohort, six subjects received PH100 and two subjects received placebo. The first cohort was dosed as a single group with PH100 (100 mg) or placebo. The subsequent five cohorts were dosed sequentially with 200 mg, 400 mg, 800 mg, 1200 mg, and 1600 mg of PH100 or placebo. Safety and pharmacokinetic data were collected and evaluated following each cohort. Dose escalation occurred after review of the safety and pharmacokinetic data from the preceding cohort(s). Doses were administered with subjects in the fasted condition.

Recruitment & Eligibility

Status
COMPLETED
Sex
All
Target Recruitment
48
Inclusion Criteria
  • Male or nonpregnant, nonbreastfeeding female;
  • Between 40 and 75 years of age (inclusive);
  • Body mass index (BMI) between 18 and 30 kg/m2 (inclusive), and minimum weight of 50 kg (110 lbs);
  • If female, subject was considered postmenopausal or surgically sterile and had status confirmed by one of the following:
  • Physiologicallypostmenopausalbasedonnomensesforatleast2years(not due to lactational amenorrhea) and follicle stimulating hormone (FSH) levels equal to or greater than 40.0 mIU/mL at screening; or
  • Bilateraloophorectomy,hysterectomy,orbilateraltuballigation(post 6 months). Or
  • If female and of childbearing potential, subject agreed to use one of the following forms of birth control from 3 months prior through 12 days after study drug administration:
  • Vasectomizedpartner(atleast6monthspriortodosing);
  • Doublebarrier(diaphragmwithspermicide;condomswithspermicide);
  • Intrauterinedevice(IUD);
  • Abstinence(agreedtouseadoublebarriermethodiftheybecamesexually active during the study);
  • Implantedorintrauterinehormonalcontraceptives;or
  • Oral,patch,orinjectedcontraceptives,orvaginalhormonaldevice (i.e. NuvaRing®).
  • If male, subject had a documented vasectomy or agreed to use a double-barrier local contraception (i.e., condom with spermicide) when engaging in sexual activity with women of childbearing potential from prior to the first dose of study drug through 28 days after the last dose of study drug;
  • If male, subject agreed to refrain from sperm donation from prior to the first dose of study drug through 28 days after the last dose of study drug;
  • Voluntarily consented to participate in this study and provided their written informed consent prior to start of any study-specific procedures;
  • Able to communicate with the Investigator, and understand and comply with the requirements of the protocol;
  • Willing and able to remain in the study unit for the entire duration of the confinement period and return for an outpatient visit;
  • Had screening blood pressure (measured sitting after 3 minutes rest) 140/90 mmHg. Out-of-range blood pressure could be repeated once; and
  • Willing and able to swallow up to eight size AAA capsules with water at dose administration. Size AAA capsules are 0.642 inches (16.31 mm) in length and 0.450 inches (11.44 mm) in diameter).
Exclusion Criteria
  • History or presence of clinically significant cardiovascular, pulmonary, hepatic, renal, hematologic, GI, endocrine (including thyroid), immunologic, dermatologic, neurologic, oncologic, respiratory, lymphatic, musculoskeletal, genitourinary, infective, inflammatory, connective tissue, or psychiatric disease or disorder or any other condition that, in the opinion of the Investigator, would have jeopardized the safety of the subject or the validity of the study results;
  • Clinically relevant history or presence of cardiac arrhythmia, narrow angle glaucoma, benign prostatic hypertrophy (men only), Hashimoto's thyroiditis, lymphocytic thyroiditis, or uncontrolled diabetes;
  • Had a clinically significant abnormal finding on the physical exam, medical history, ECG, or clinical laboratory results at screening;
  • History or presence of allergic or adverse response to PH100 (product names: Seapolynol, Fibroboost, Fibronol, Seanol Longevity Plus, Circulate, Alginol, PC Ecklonia Cava, Seanol, Seanol-F, Seanol-EX, Seanol-TX, Venusen, Memories with Seanol-P, Astaxanthol, Brilliant Vision with Seanol-P, Gly-Control, Gyne-Andro-Plex, Lipid Balance, Seanol with Broccoraphanin, and Marine D3) or related drugs;
  • Had used PH100 (product names: Seapolynol, Fibroboost, Fibronol, Seanol Longevity Plus, Circulate, Alginol, PC Ecklonia Cava, Seanol, Seanol-F, Seanol-EX, Seanol-TX, Venusen, Memories with Seanol-P, Astaxanthol, Brilliant Vision with Seanol-P, Gly-Control, Gyne-Andro-Plex, Lipid Balance, Seanol with Broccoraphanin, and Marine D3) as a supplement within 30 days prior to the first dose of study medication;
  • Had been on a significantly abnormal diet during the 4 weeks preceding the first dose of study medication;
  • Had donated blood or plasma within 30 days prior to the first dose of study medication;
  • Had participated in another clinical trial (randomized subjects only) within 30 days prior to first dose of study medication;
  • Had used any over-the-counter (OTC) medication, including nutritional supplements, within 5 half-lives or 14 days (whichever was longer) prior to the first dose of study medication;
  • Had used any prescription medication, except hormonal contraceptives for women of childbearing potential or hormone replacement therapy, within 5 half-lives or 14 days (whichever was longer) prior to the first dose of study medication;
  • Had ingested drinks or foods containing grapefruit or St. John's Wort within 14 days prior to the first dose of study medication;
  • Had been treated with any known drugs that are moderate or strong inhibitors/inducers of CYP enzymes such as barbiturates, phenothiazines, cimetidine, carbamazepine, etc., within 30 days prior to the first dose of study medication and that in the Investigator's judgment may have impacted subject safety or the validity of the study results;
  • Had discontinued the use of implanted, intrauterine, or injected hormonal contraceptives less than 6 months prior to the first dose of study medication;
  • Had discontinued the use of oral, patch, or vaginal hormonal contraceptives less than 1 month prior to the first dose of study medication;
  • Had smoked or used tobacco products within 6 months prior to the first dose of study medication;
  • Had a history of substance abuse or treatment (including alcohol);
  • Was a female who had a positive pregnancy test result or was nursing, lactating, or trying to become pregnant;
  • Had a positive urine screen for drugs of abuse (amphetamines, barbiturates, benzodiazepines, cocaine, cannabinoids, opiates), alcohol, or cotinine;
  • Had a positive test for hepatitis B surface antigen (HbSAg), hepatitis C antibody, or human immunodeficiency virus (HIV) at screening or had been previously treated for hepatitis B, hepatitis C, or HIV infection; or
  • Had difficulty swallowing up to eight capsules.

Study & Design

Study Type
INTERVENTIONAL
Study Design
SEQUENTIAL
Arm && Interventions
GroupInterventionDescription
Control for 100mg DosePlacebo1 placebo capsule (n=2)
Control for 400mg DosePlacebo2 placebo capsules (n=2)
Control for 1600mg DosePlacebo8 placebo capsules (n=2)
100mg DosePH100 100mg1 x 100 mg PH100 capsule (n=6)
Control for 800mg DosePlacebo4 placebo capsules (n=2)
Control for 1200mg DosePlacebo6 placebo capsules (n=2)
200mg DosePH100 200mg1 x 200 mg PH100 capsule (n=6)
400mg DosePH100 400mg2 x 200 mg PH100 capsules (n=6)
800mg DosePH100 800mg4 x 200 mg PH100 capsules (n=6)
1200mg DosePH100 1200mg6 x 200 mg PH100 capsules (n=6)
Control for 200mg DosePlacebo1 placebo capsule (n=2)
1600mg DosePH100 1600mg8 x 200 mg PH100 capsules (n=6)
Primary Outcome Measures
NameTimeMethod
Hemoglobin (g/dL)48 hours postdose

Safety Assessment in Hematology

Leukocytes (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Basophils (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Neutrophils (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Calcium (mg/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Chloride (mmol/L)48 hours postdose

Safety Assessment in Serum Chemistry

Creatinine (mg/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Albumin (g/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Glucose (mg/dL)48 hours postdose

Safety Assessment in Urinalysis

Leukocyte esterase (/uL)48 hours postdose

Safety Assessment in Urinalysis

Incidence of treatment emergent adverse events96 hours postdose

Subjects were instructed to inform the study physician and/or research personnel of any AEs that occurred at any time during the study. Subjects were monitored for AEs from the beginning of confinement through the end-of-study visit (96 hours after dose administration). Reported or observed AEs were documented and followed to resolution.

Hematocrit (%)48 hours postdose

Safety Assessment in Hematology

Basophils/Leukocytes (%)48 hours postdose

Safety Assessment in Hematology

Platelets (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Serum Glucose (mg/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Aspartate phosphatase (U/L)48 hours postdose

Safety Assessment in Serum Chemistry

Specific gravity48 hours postdose

Safety Assessment in Urinalysis

Occult blood (/uL)48 hours postdose

Safety Assessment in Urinalysis

Change from Baseline Body Temperature (degrees C)2, 4, 48, 96 hours postdose

Safety Assessment in Vital Signs

QTcB interval (ms)48 hours postdose

Safety Assessment in ECG

Erythrocytes (10^6/uL)48 hours postdose

Safety Assessment in Hematology

Eosinophils/Leukocytes (%)48 hours postdose

Safety Assessment in Hematology

Lymphocytes (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Lymphocytes/Leukocytes (%)48 hours postdose

Safety Assessment in Hematology

Alkaline phosphatase (U/L)48 hours postdose

Safety Assessment in Serum Chemistry

Monocytes/Leukocytes (%)48 hours postdose

Safety Assessment in Hematology

Potassium (mmol/L)48 hours postdose

Safety Assessment in Serum Chemistry

Urate (mg/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Monocytes (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Eosinophils (10^3/uL)48 hours postdose

Safety Assessment in Hematology

Neutrophils/Leukocytes (%)48 hours postdose

Safety Assessment in Hematology

Sodium (mmol/L)48 hours postdose

Safety Assessment in Serum Chemistry

Blood urea nitrogen (mg/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Alanine transaminase (U/L)48 hours postdose

Safety Assessment in Serum Chemistry

Total bilirubin (mg/dL)48 hours postdose

Safety Assessment in Serum Chemistry

Lactate Dehydrogenase (U/L)48 hours postdose

Safety Assessment in Serum Chemistry

pH48 hours postdose

Safety Assessment in Urinalysis

Nitrite (Negative/Positive)48 hours postdose

Safety Assessment in Urinalysis

Bilirubin (mg/dL)48 hours postdose

Safety Assessment in Urinalysis

Urobilinogen (mg/dL)48 hours postdose

Safety Assessment in Urinalysis

Change from Baseline Diastolic Blood Pressure (mmHg)2, 4, 48, 96 hours postdose

Safety Assessment in Vital Signs

Change from Baseline Pulse Rate (bpm)2, 4, 48, 96 hours postdose

Safety Assessment in Vital Signs

Change from Baseline Respiration Rate (Breath/Min)2, 4, 48, 96 hours postdose

Safety Assessment in Vital Signs

PR interval (ms)48 hours postdose

Safety Assessment in ECG

QTcF interval (ms)48 hours postdose

Safety Assessment in ECG

Change from Baseline Systolic Blood Pressure (mmHg)2, 4, 48, 96 hours postdose

Safety Assessment in Vital Signs

ECG heart rate (bpm)48 hours postdose

Safety Assessment in ECG

QRS complex (ms)48 hours postdose

Safety Assessment in ECG

QT interval (ms)48 hours postdose

Safety Assessment in ECG

Secondary Outcome Measures
NameTimeMethod
Change in Blood Concentration of dieckol (ng/mL) by HPLC-MSat 0, 15, 30, and 45 minutes, and 1, 1.5, 2, 3, 4, 6, 8, 12, 16, 24, 36, 48, and 96 hours after dosing.

Pharmacokinetics of 8,8'-bieckol, a major compound of PH100, after single, ascending, oral doses (100 mg, 200 mg, 400 mg, 800 mg, 1200 mg, and 1600 mg) of PH100 in normal healthy volunteers.

Change in Blood Concentration of 8,8'-bieckol (ng/mL) by HPLC-MSat 0, 15, 30, and 45 minutes, and 1, 1.5, 2, 3, 4, 6, 8, 12, 16, 24, 36, 48, and 96 hours after dosing.

Pharmacokinetics of 8,8'-bieckol, a major compound of PH100, after single, ascending, oral doses (100 mg, 200 mg, 400 mg, 800 mg, 1200 mg, and 1600 mg) of PH100 in normal healthy volunteers.

Change in Blood Concentration of PFF-A (ng/mL) by HPLC-MSat 0, 15, 30, and 45 minutes, and 1, 1.5, 2, 3, 4, 6, 8, 12, 16, 24, 36, 48, and 96 hours after dosing.

Pharmacokinetics of 8,8'-bieckol, a major compound of PH100, after single, ascending, oral doses (100 mg, 200 mg, 400 mg, 800 mg, 1200 mg, and 1600 mg) of PH100 in normal healthy volunteers.

Trial Locations

Locations (1)

Worldwide Clinical Trials Early Phase Services, LLC

🇺🇸

San Antonio, Texas, United States

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